THA showed reproducible XRPD profiles, but THM showed fluctuating intensities in some specific peaks in the profiles. The linear calibration models were evaluated based on calibration XRPD datasets of the standard materials by various methods. In the result based on validation XRPD datasets, the order of the mean bias and the mean accuracy were peak height > peak area > Wakelin’s > PCR, indicating that PCR was the best method to correct sample crystal orientation. The effectiveness of the PCR method in construction of calibration models was

discussed by a scientific approach based on regression vectors.”
“Epoxidized soybean oil (ESO) triglycerides were reacted with maleinized polybutadiene (MMPBD) to give plant-oil-based thermoset

polymers. MMPBD samples were of two different molecular weights [high-molecular-weight selleck chemical maleinized polybutadiene (MMPBD-H), maleate content = 10%, number-average molecular weight (M(n)) = 9000, and low-molecular-weight maleinized polybutadiene (MMPBD-L), maleate content 15%, M(n) = 5000]. To increase the crosslink density of the product, a free-radical initiator, benzoyl peroxide, was added to this mixture to further crosslink MMPBD through its double bonds. The characterizations of the products were done by dynamic Ganetespib in vivo mechanical analysis, differential scanning calorimetry, thermogravimetric analysis, and IR spectroscopy. The ESO-MMPBD polymers were crosslinked rigid infusible polymers. ESO-MMPBD-H-1 : 1 and ESO-MMPBD-L-1 : 1 showed glass-transition temperature values at -23, 78 and -17, 64 degrees C, respectively, whereas the storage moduli of the two polymers at 25 degrees C were 13 and 16 MPa, respectively. The storage moduli of the polymers remained the same or decreased with the addition of a free-radical initiator. The storage moduli also decreased with increasing ESO concentration above a 1 : 1 epoxy-to-anhydride

MGCD0103 molar ratio. The surface hardness increased dramatically, and the equilibrium swelling ratio decreased with the addition of free-radical initiator. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 120: 116-123, 2011″
“Background: Chronic obstructive pulmonary disease (COPD) is a progressive inflammatory lung disease associated with increasing morbidity and mortality and an economic burden that stretches beyond the patient to healthcare systems. Avoiding exacerbations and subsequent hospitalizations is an important clinical aim and can avoid significant costs associated with the disease. International guidelines recommend the addition of an inhaled corticosteroid (ICS) to a long-acting beta(2)-adrenoceptor agonist (LABA) for patients with severe to very severe COPD and a history of exacerbations.